Drop some sand in a cup with vinnegar, if the sand fizzes like alkaseltzer then it is aragonite based. If it doesn't fizz it is silica based. Something in the aragonite sand has a chemical reaction with the vinnegar and that's what makes it fizz!
Aragonite sand is better as it helps buffer the Ph levels in your tank, and if you research silica sand a lot of people have had problems using it in aquariums!