GH, or general hardness, is a combination of Calcium plus Magnesium ions. But it would be very rare to have a water supply high in magnesium but low in calcium; usually the opposite is true, and calcium makes up a much greater percentage of the hardness in
GH. So effectively, if you have high
GH you can safely assume you have a pretty high level of calcium.
KH is carbonate hardness. It may have some accidental relationship to calcium (and often does) but there is no guarantee in that at all. So
KH, of itself, is not of any particular value in determining the calcium content of the water.
GH is a much better test of that.