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Welcome to AA! What size tank are you considering? I feel you would be better of doing a school of them with neons and sterbais Cories. Depending on the size . Hope you like the site so far!
Ive seen discus kepts with freshwater rays and german blue rams with a school of cardinal tetras and to top it all off, angels.. Super nice setup wish i had a pic.. Idk how/why these ppl did it but its definatly not sugested to keep them with gouramis or angels for thet matter. And im not very knowledgeable on freshwater rays
Yeah angels are aggressive and would not be good with discus. Freshwater rays are from South America like discus and if the tank is big enough they can be tank mates. Rays are shy bottom feeders that won't bother the discus.