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IMO just one DG to a tank, if anything goes wrong and you cannot upgrade, the male or possibly even female can turn out to be aggressive and bully the other sex to death. I wouldn't add anything until your tank can handle quite a bit of bioload.
 
Ok, so if you kept the dg in there then you would need to test the water every day. When there are 0 ppm of ammonia and nitrites then I think you will be able to add another fish.
 
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