Try adding some Epsom salts I am not the science major here but it helps stability of KH, also you can always get some, very important mineral - magnesium sulfate.
I have 0 kh in my tap.
I add up to 1 tablespoon per gallon of Epsom Salts, you can start with 1.5 tsp p/g probably would be good.
Then also add Kent Marine, Superbuffer-dKH (in FW) at the rate they list on the package per gallon.
Also a pinch, maybe 1/8 or less of tsp of baking soda when doing a 25-30G pwc.
Rarely will add a couple TBL's (for a 72G tank) of natural mineral salt called Orso salt, aka Redmond or Real brand salt - I get it at the health food store where it is a few dollars for a couple pound bag. Maybe 4 times a year when changing the canister filter. That is mainly when I think about it. I guess this isn't necessary but when I used to add this all the time in my tanks - as in every water change I never had a pH issue. After I stopped using salt hearing it was not good for the fish, there were more issues. Annecdotal input.
This has helped my tanks out greatly with the unstable pH issue, in regards to the calcium and magnesium.