It CAN indicate poor water quality, but one snail climbing to the top doesn't necessarily mean anything at all. If in doubt, test the water to be sure. Assassins prefer eating other snails, but I am not sure how they hunt. If it's by smell, I'd expect them to follow the scent of other snails. If they hunt by sight, I'd expect them to be moving a lot, looking for other snails.
If they hang at the top and don't leave it, I'd test the water to be sure there isn't any problem. If no problem, might just be an odd ball snail. They don't often have many problems, so I tend not to worry too much about snails, unless I see damage on their shells or they have not moved from one place for more than a day or so, in which case I'll check to be sure they are alive. Nearly always are alive, btw.