Another way to kill live rock would be to take it out of the tank and leave it exposed to air for a few weeks.
Even with rock thats been exposed to copper it kind of sort of is still alive with bactera. I mean if they sell that bagged sand as live sand when its just covered with bactera (supposedly) then the same could be said for the rock in the tank.
Dieing live rock will smell very foul. It will smell like its dead from all the small lifeforms that are decomposing on the rock.