It really depends on if it is a reef tank or FOWLR. If it's a reef tank, you should set timers as follows:
Full Spectrum 10,000's run from 8:00 am - 8:00 pm
Actinic's run from 9:00 am - 7:00 pm
Lunar LED's run from 8:00 pm - 8:00 am
FOWLR is simply 10:00 am - 8:00 pm for both 10,000's and Actinic's and LED's the opposite
Make sense?