Thanks to all replies.
For Nitrates level, you guys are correct about having it reduced by approx 10 ppm with a 25% pwc. Im sorry I forgot to mention that my tank is just a month and half old and not fully matured yet. Also its unfortunate that I've already set it up before I discovered this site. Because of that I ended up with 2 Marineland C-360 canister filters (1 on each end) which I read that could also cause problems with Nitrates. I just installed a Coralife Super Skimmer 65G but I know may not be enough. I'm also going to change the media that I have in my filters with either GFO or Chemipure to hopefully help bring my nitrates to 0 so I can start transitioning to a reef tank maybe in the next 6 months or so when my system is already matured.
As for my Nitrates readings, those numbers I mentioned above are direct readings and has not been divided by 4.4 So if the correct way is to divide by 4.4 then my 20 ppm is actually 4.54 If that is the case then I dont really need the 25% pwc. That's why it would greatly help me if I can understand the difference. Once again thanks to all your replies.