I've heard this question asked on numerous sites and have never found a definitive answer. I have heard a number of times that the production of it creates by-products and is also occasionally treated in order to hold it's form. If that's true, I'm not sure it'd be a safe bet and definitely worth searching for a bottle of the pure stuff from a local hardware store.
Plus, with some of the things ammonium nitrate has been used for in the past...the Department of Homeland Security might have some questions for you when you go to buy it, lol.