Measuring CO2 levels in a Planted Tank
Check out that link. About 3/4 of the way down the page there is a chart that will help you determine your co2 level. I would say that with those readings, your co2 concentration is too high. This is probably why your fish were swimming near the top.
KH is a measure of the alkalinity of your water based on the amount of carbonate and bicarbonate your water contains.
So you know, ammonia and nitrite are toxic to fish. You want to keep them both as low as possible. You can change 50%+ of your water every day to keep these numbers low.
The best test kit is the Freshwater master test kit by API. The liquid titration tests are far more accurate than the dip strips.
10ppm nitrate is ok. Nitrate doesnt start to become toxic to your fish until it gets to much higher levels. 50+ really, but 20+ is no good to be safe.
As far as the lighting... it is not ideal, but it will probably work. My concern with it would be that you may get algae that can use more of the light at that color temperature than your plants can. Ideally, you want to get the color temp a little lower to maximize plant absorption and minimize algae taking over. When you start getting into powerful lighting and co2 addition just be aware that you may need to start dosing fertilizers - some kind of trace, a nitrogen supplement, potassium supplement, and a phosphorus supplement. If you have too much light, too much co2, or too much fertilizer, it can really encourage algae growth. You really have to try to balance all of these, especially in a high tech setup like you are starting. These setups are great, it is just things can take a turn for the worse a lot faster than in a low light, low tech setup.