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doesn't acrylic "cut" best with a scoring knife and breaking it? that's how I've always done it. the knife is a $3-4 part at the hardware store. Use a straight edge and score the acrlyic with the knife 2 or 3 times, place the acrlyic on the edge of the table and snap off the piece your cutting
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You can do it that way, but it is soooooo much easier to cut it with a table saw, assuming you have a table saw of course. Especially when you are using 1/4" or thicker acrylic. When using a scoring knife, if you don't score it deep enough and go to hit it, you can easily crack it. You might as well throw the sheet out if that happens.
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Would joining acrylic to glass work with silicon?
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Sure. I have done it many times. So long as the acrylic is thick enough so that it doesn't "bow" out. Of course if equal amounts of water is on both sides of the acrylic this won't happen. If you are joining acrylic to acrylic you need to use Weld-On #3.