I'm no vulcanoligist (no nothing to do with Startrek

) but IIRC the pumice is formed at the start of the eruption when the molten lava is under pressure and the gasses and steam expand inside the liquid rock and if it cools quickly enough they get trapped giving it a sponge like structure.
Visualise what would happen if you were to shake a cola and open it - if you could freeze it at that moment you'd have a cola version of pumice.
Some is light enough to actually float
It's very easy to work and has good porosity.
A