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I have read books that say to top off your tank as needed with Fresh RO water. Would it be ok to top off with extra mixed water you have laying around from a previous water change? Or should that water be dumped after some time?
No, you'll raise the SG if you top off with SW. When water evaporates, that's all the evaporates... everything else stays behind. You're replacing the water to keep the SG the same.