Aging tap water is not *nearly* the same as a good
RO/
DI unit. If you age your tap water it will very likely still have a
TDS of 150 or so (some areas much worse). That stuff doesn't belong in your tank. The salt that is added to the
RO/
DI water is formulated to put into that
RO/
DI water all of the necessary elements for reefkeeping (as close as synthetic can get to Mother Nature). Saltwater should age for 24-48 hrs after mixing anyway so that the salt can properly dissolve.
That being said, I started my tank on tap water and it probably still has quite a bit of tap still in it, but I also bought an
RO/
DI unit for 100$ off of ebay from FilterDirect and have been using that ever since.
I always have 30g stored in 5g containers ready for use.