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That's sperm and you might see eggs too. I don't have personal experience but I've heard it will rot and overload your biofilter without major water changes. Can you move the urchin to an isolation tank until it quits trying to reproduce?
It's quite fascinating. You could see it oozing from his pores then wisping away like smoke. Haven't seem it anymore today. I wonder what the frequency is or if anything specific will trigger it.