I agree with Roscoe about using a nano glass diffuser in a tank that small... good method to use.
Using a powerhead is a GREAT method for diffusing
CO2. It is usually referred to as "misting". I tried it for a time with excellent results as far as plant health. What I mean though about the bubbles is that the powerhead really chops up the
co2 into a fine mist, and those bubbles are so small that they don't float straight to the surface (since the powerhead is blowing them outwards). What happens is these bubbles, being so small, will get trapped in the water (like if you quickly poor a bunch of water into the tank, you will have a bunch of tiny microbubbles for a time). It is great for the plants. It ensures near complete diffusion of the
CO2, and some of it even gets trapped under plant leaves as a side benefit, resulting in direct diffusion into the plants. Like I said, it worked great in my tank... but I got sick of the water clarity suffering from all the tiny microbubbles in the water column, so I stopped doing it and moved back to using glass diffusers. The bubbles are the same size coming out, but since they aren't being blown outwards in a turbid stream, they tend to float straight up, and thus don't hang out in the water column. Less diffusion, but also less annoying bubbles floating around

.
Does that make sense?