Unless you want to take the time to cure natural seawater, or you are getting from an aquarium of
LFS. I would go with the salt mix. You would have to let the
NSW cure to allow for plankton die off etc and depending on where you collect it, it could contain any number of pollutants. I've been having good results with Kent Sea salt, Tropic Marin is another good one, Insant Ocean etc...it somewhat depends if your tank is
FO or reef, some salts are better at maintaining water chem for reefs
IMO HTH