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Thanks ScotJudd!
I'll find it difficult to not do a water change - I like the reassurance of it!
Am not planning to add more fish - I think the 5 neon tetras are plenty (and in fact from further reading, the tank is too small for them, so am looking at getting more appropriate inhabitants)
I have a Fluval edge (6 gallon) which was set up with live plants (on birch wood) from my LFS's tank. 5 neon tetras were added a couple of days after tank set-up.
I've been a bit obsessed with water testing, given the fish are in there. I'm wondering what my results actually mean though, given...