I would stay away from any kind of lava, and stick to aragonite. Lava has wildly varying chemical composition depending on where it came from, and saltwater has a nasty habit of oxidizing any metallic compounds it comes in contact with. This isn't a problem if it is the light metals like calcium, magnesium or strontium. Those are necessary for life, and it quite high concentrations. The problem comes when you start getting into the heavier metals like iron, copper, zinc, aluminum or lead. Iron, copper and zinc are all essential for life in small amounts, but if the concentration is too high they can quickly become toxic.
In the ocean this isn't an issue because what ever leaches out of fresh lava that comes out into the sea is diluted by literally trillions of gallons of water. The same cannot be said about your aquarium.