Yeah, the wetdry is going to outgass all your CO2.
There is significantly less reason to put a sump under a freshwater tank than under a saltwater tank.
There are more discreet fill valves than the toilet type if you want to implement this in the main tank.
Expensive solution:
2 electronic float switches and 2 solenoid controled valves, plus some minor electrial equipt...
1. Push button on controller, opens drain valve.
2. Drain point float switch triggers drain valve closed, fill valve open
3. Fill float switch triggers fill valve closed.
For a real fancy system, have the drain point float switch also trigger a dosing pump to put in your dechlor, and have the whole thing on a timer that does the whole water change for you.
Might add a third float switch above the other two as an emergency shutoff. Should the fill valve fail, it would turn the whole system off when the uppermost valve got wet.