Ahhh, interesting! Ok, so my guess is that you had some BBA (black beard algae). If its wasn't than you can ignore my sentiments. BBA primarily is evidence of unstable Co2 levels. On the other hand, if you have too few plants to absorb nutrients, and your water saturated with excess nutrients and your light is really high, algae blooms! So my questions: What size tank you do have, and why did you go with 12k (as opposed to 6.7k or 10k) for your freshwater tank? How do you plan to regulate your Co2 so the incredibly high amount of light that you run won't cause another algae bloom?
As for enjoying the tank, I think you'd be fine running a 12 hour day, or a little more, and the leaving the lights off while you sleep. Fish aren't from another planet, they're all used to the same days we are. They, like us, won't die from having strange sleep cycles, but how would you feel if you slept every day from 12-4, then worked out till 8, then when back to sleep for 8 hours, then woke back up at 8, worked till 12, and so on? But I'm just trying to sway your opinion, i don't have proof that it hurts the fish.