The greatest favor you can do yourself in terms of pH balancing is to not use store-bought chemicals. These have only temporary effects, and commonly harm the fish.
For increasing pH, your best option is to go natural. Buy yourself a small bag of crushed coral, and a mesh bag or two. Transfer the coral to the mesh bag and wash the whole bag to make sure that you get out any particulate matter that will fit through the apertures in the mesh. If you wish, you can also crush the coral a little more yourself to add surface area. Then, add the crushed coral mesh bag to your filter. You will find that the
KH of the water will increase quite quickly, and that the pH will increase accordingly.
For decreasing pH, your best option is, again, natural. 2 choices. Adding Malaysian (or African Swahala) driftwood to the main body of your tank, or adding peat to your filter. Hagen sells peat for their Fluval line of canister filters, and peat or peat moss (
Sphagnum spp.) can also be found quite simply in bogs (cheaper, but harder to get). Both should lower the pH of your water.
As to the reason for the difference in the first place, I'm stumped. I can only guess that some of the ornaments, or the substrate you have, are influencing the pH. More concretely, my guess is that the
KH (buffering capacity) of your tapwater is low, allowing pH to swing greatly between lows (6.6) and highs (8.0). It might be a good idea to have a little bit of crushed coral in both tanks in order to buffer the
KH of the tank, and protect your fish from sudden pH swings.