If the water is not "doctored", your
KH consists of mostly bicarbonates. There is a fixed relationship between
CO2 level, bicarbonates & pH. Assuming that your water is equilibrated with air, & there is no injected
CO2, the
CO2 in the tank MUST be approx. 3
ppm. With a
KH of 7, the pH should be 7.6 or so.
When you test the water & the measured
KH & pH don't give a normal atmospheric
CO2 level, 2 things can be true:
1. You have excess
CO2 in water (this is often seen in well water), in that case the
CO2 will escape & the pH will rise over 24 Hrs or so to the theoretical value.
2. The
KH is NOT all bicarbonates - eg. there is nitrates, phosphates or other buffers in the water, or you have added pH down, etc. In that case you cannot use any of the
KH/pH/
CO2 calculators on the net - as all of them calculates
CO2 levels assuming that the
KH is 100% bicarbonates.
When you have a mixed buffer situation, the only way to know the
CO2 level is to measure it directely. (I am not sure of the
CO2 test kits on the market - if they actually measure
CO2 directly or indirectly. I normally measure
CO2 using infared absorption &/OR Mass Spectrometry.)