+1 I fill up buckets firstI treat the water I'm adding before it hits the tank. That way I use a smaller amount.
It's kind of up to you. If add your water straight to the tank then treat the entire volume of the tank or if you use buckets then just dose the buckets. Both ways are perfectly safe.
To be clear, are you saying that for a new setup, it's fine to fill and then treat or are you adding untreated water to a tank with fish in it and then adding the dechlorinator? I was always taught to treat and age the water 24 hours before adding to let it gas off and come to room temp. So, that's what I do. I was using plastic gallon jugs for the small tank and a medicine syringe to measure the amount for a single gallon. I'm now shopping those camping water totes so I don't have open buckets of water sitting around for the 65.
No I am saying I use a water changer I suck the water out and then add a capful of prime which is more than enough for the 36g bf tank and fill the tank straight from the tap. Once you use the de-chlorinator the water is perfectly safe of immediate use. There is no need to let the water sit for any length of time after it is used. The only time you need to let it sit is if you don't have a de-chlorinator.