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Im not sure exactly what it is, but its quite common in new tanks. Could be a type of algal growth or it could be a biofilm. In any case its harmless, just scrape it off your glass.
Sorry for the delay. Most recently - the tank was 0/0/20. We scraped the white stuff off - some of the fish even picked at it. I was worried that tank was in trouble. It did not cause a problem.
We do have some brown algae now -- we just scrape that too. Possibly related...