This is a situation where the results we hypothesize do not lineup with our results. Thus, we must conclude that the original hypothesis is flawed.
Imbalance is a crap term that has, unfortunately, caught on within the hobby. It all comes down to Liebig's Law. Essentially, the only nutrients that matter are the ones that are two low, and hence limiting to the system. For instances, if I need to make a widget and need 20 of part A, 5 of B, and 1 of C, and I have 1000 of A, 1000 of B, and 5 of C, then I can only make 5 widgets. The number of A and B ultimately don't matter. If, however, I have 1000 of A, 100 of b, and 100 of C, B is now limiting. As I understand it, in nature, phosphates are often the most limiting factor, hence why phosphate releases often cause massive algae blooms. In aquariums though, phosphate are usually is excess because our aquariums are stocked at levels many times that of an actual lake. Thus, they are fundamentally different than the systems studied in limnology. It hasn't been as well studied academically, but if I had to guess, I would say that the limiting factors in aquariums are either CO2 or light, depending on the setup.
PMDD is an outdated dosing method that tries to recreate this. It's more modern version is PPS.