oil slick

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You need more surface agitation. Add a powerhead or reposition your filter output. And it should go away.
 
i had that one time and couldnt figure it out! come to find out, i never plugged my filter back in! haha
 
It can also be caused by having something like hand cream on your hands and putting them into the tank.
 
From what I figured out it is a build up of organic proteins, more surface agitation from your filter or a bubbler should clear it up with in an hour.
 
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