I might be able to offer some info here.
The water company I work at adds ammonia to the water just before it leaves the plant. The ammonia combines with the free chlorine to form chloramines. They usually feed a little more ammonia than is needed to make sure that all of the chlorine is bound up. If they feed more ammonia than that, you will see it as free ammonia.
Something else that comes to mind is what kind of de-chlorinator are you using? Others with more knowledge will chime in but check the bottle and see if it is made to treat chloramines. I think that if it is not, then you may be freeing up the ammonia portion of the chloramines and it is showing up in your test.