From the link posted above....
"Substrate Types Commercially Available:
Quartz, silicate,
SiO2 sand, the plain masonry/builder's variety is promoted by some hydrophyte growers, but I don't particularly care for it. Silicates are non-nutritive, unreactive, sharp-sided and tend to pack down. Their best quality is price; typically very cheap. If you're settling on quartz, look (bring a hand lens) for one that is more spheroidal than two-dimensional, and avoid "play sand" grades. You want a coarser, #15 (i.e. fifteen average pieces per linear inch) or lower (that is larger size) number grade.
Other silicates:Crushed glass, marbles. One's too sharp, both are too microscopically smooth.
Flints, are crushed silicates; they are good-looking and cheap in areas of origin, but can be a little sharp for catfishes and other livestock that cut easily.
Volcanic crushed rock, cinders; this igneous rock is unsuitable for the same reasons as all the other silicates mentioned above; it's too sharp edged, and lacks porosity and buffering action.
Coated Gravel, colored or not, pebble or flat pieces, are also inferior in my opinion. Aesthetic considerations aside (maybe you like pink and lime green together!), epoxy, et al. coated gravels lack surface area and possible mineral contribution. Worst case scenario are some off-brands of sealed dolomitious material that aren't quite sealed. Beware these that don't rinse clear on rinse-cleaning.
Calcareous Gravels and Sands Dolomite, Marble, Coral Sand, Marine shells, etc.: are compounds of varying make-up of calcium and magnesium carbonate. Some "soft" dolomites are quite soluble; all calcareous substrates should be used only with plants that prefer or will tolerate hard, alkaline water. These are few.
"Natural Gravels"; are my hands-down favorite choices. The best of these are "river-run" collected; they're blends of hard silicates, including basalt, feldspars, granite and more. The commercially bagged varieties are graded, angular, and alkaline enough to be of near-optimum use for aquatic gardeners."