Hi fishy Steve,
IMHO, an angel would not be appropriate for a 20 gal, even a tall one. The only scenario where I could see that happening is when they are very small and have a larger tank to go into as they get bigger, but personally I don't prefer to keep fish in small temporary setups unless it's necessary (quarantine).
In my experience, angels like to move all over the tank, and they are territorial to a point. Once you have gravel, decor, and everything else in your tank, even one adult is going to feel cramped, especially with other fish. In addition, I'm not sure what type of filter you have but if it's an HOB there's not a lot of room for an angel to move away from the outflow.
For that size tank, there are a lot of other neat fish to consider, tetras, rasboras, dwarf rainbows, dwarf cory species, shrimp, snails, and so on. I would suggest looking around some more before you make a final decision.