I haven't had a leaky tank, so take this as you will..
Use an Exacto blade to cut the corner out (slide into corner while flat on glass, both sides) do NOT dig into the corner, but make sure the tip is into the corner (you can go flat on the glass and put the blade into the corner repeatadly), the old silicone should just fall off.once you have a nice clean corner and about 1/4" out on each side clean, apply the new sealant, use your finger to press it into the corner (press hard to make sure air escapes), you should end up with a nice beveled corner.
Masking tape or any tape really can be used to mask the area outside 1/4 inch to make clean up easy, just make sure the tape is removed before the silicone sets, otherwise you may break the seal. allow it to set for 24 hours before leak testing the new corner. (do not try to seperate the glass, there is a thin layer between the 2 sheets, and it's not as easy to redo, and often not necessary.) just clean the inside of the corner and make sure there is no residual silicone, (silicone adheres to glass better then itself)
hth, and please read some other thoughts on this, hope the explaination is alright.