I would ask this question in the fw 'planted tanks' forum because you will get a better response. I dont fully understand the process but there is something called 'biogenic decalcification' which relates to GH & KH and your co2 system and how your plants utilize everything and the end result is a big jump in ph. I believe it has something to do with specific plant species & their production of carbonate. Someone with more plant & co2 experience will be able to explain whats going on (im still learning!)!! Good luck!