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I have had a gold and blue gourami with cherry shrimp, otos, cardinals, and galaxy rasboras, never bothered any of them. So guppies should be alright. But don't expect to see any babies!
not too sure if all gouramis do pick on guppies, but i had a guppy before i introduced my dwarf gourami to the tank and the dwarf gourami as soon as it was introduced to the tank like a day later i noticed it loved picking on my guppy. so my guppy ended up dieing about 4 days later.i was so mad cuz i was attached to the guppy and i think guppies in general are really cute peaceful fish. so i cant get anymore cuz it will kill any new guppys.so i guess u can be taking a risk on getting a gourami that loves to pick on the guppies, some may and some may not