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Vinegar and baking soda is the houswife cleaning combo for everything! Well, at least it takes the smell of urine out of the mattress when your two year old wets. haha. I use the two together to clean a lot of things though. Not sure if that's why the OP did it though.
Haha, ok I knew vinegar was good for removing hard water stains, but since baking soda is just sodium bicarbonate I wasn't sure what purpose it served.