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When I set up my 100g I was going on mostly past experience (which is limited at best with SW) and i went with crushed coral. Is it too late to add sand now that my tank has cycled and i have fish in it ?
It would be best to replace about 1/4 of the cc each week till it's all sand. Many folks have done it. Do as search and you should find quite a few threads on that topic.
You want to have some sort of barrier that goes front to back to keep the 2 substrates separated while you change it out.
No i don't have a quarantine tank yet and I was thinking if i go for it, removing about half the crushed coral and replacing with sand. I'm assuming that will increase my bio-filter?
If it was me I would siphon up 1/4 areas of the substrate and then use a piece of PVC and slide the rinsed new sand down to the area you need it at. Then in a week or two move to the next 1/4 area and keep doing it till all the CC is gone and tank is all sand.