pH will naturally lower as a tank matures, due to the acidic nature of fish waste. The risk present with low pH is that some of the nitrifying bacteria don't work much, but the ammonia converts to ammonium at low pH, which is good for the fish. The problem comes when you do lots of water changes to raise the pH, quickly converting that ammonium back to ammonia, and killing the fish. This is why so manyh people will say they don't ever do water changes and the fish are fine, then they all die when they finally do decide to do water changes.
Just a cautionary tale against drastic water changes to correct the problem. The only thing I can think is that this tank has been set up longer than the rest, is that true? If not I will really have to put my thinking cap on.
Crushed coral in the filter should help quite a bit, as will a generalized slow, gradual increase in the frequency of water changes, assuming your tap water is more alkaline that what you have in the tank.
Good luck and post back with more info if I have it wrong