My personal choice would be Pelvachromis Pulcher (Kribensis).
They stay small enough to fit comfortably in the 20G, they are also great parents.
And as far as interesting and exciting habits go, the 'show' that they put on for each other during the mating ritual, fascinates my whole family.
The female's belly changes to a deep burgundy color, and she will arch herself sideways to make herself look big and round (probably to signal that she is full of eggs). Then they both take turns swimming in front of each other and 'jiggling'
(My daughter says that it looks like they are being electrocuted).
If the conditions are right, it takes no time at all... I introduced a male Kribensis to my tank, we found eggs after 3 days and had about 40 fry within 10 days.
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