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You can try Pets Inc. It is at the NE corner of Southern/Mill in Tempe. They have a big selection of FW and SW fish. Lots of equipment as well.
Another place would be Phoenix Tropical. It is an older place that sometimes has a good selection of fish and other times its so so.Not much in the way of equipment since its small. They are on 37th street about 4 blocks north of Thomas in Phoenix.
the last place I can think about is place right off of I-17/Thomas just east of I-17. Can't think of the name but its a huge place. Lots of tanks and equipment, some SW fish but the FW fish selection is not any better the Petsmart/Petco.
Between the 3 places I like Pets Inc. the best. Overall they have the best selection of stuff and the best prices. Phoenix Tropical would be second