My idea doesn't really make sense given the high nitrate reading, but i thought I'd throw it out there...
Has your tank temperature been temporarily lowered recently? Nitrobacter (Nitrite -> Nitrate) are more sensitive to low (<76F) temperatures than Nitrosomonas (Ammonia -> Nitrite), so a temporary drop in temperature could cause a nitrite spike. I think the reason this isn't too much of a problem in coldwater tanks is that the Nitrobacter adapt to the lower temperature, but a transient change (e.g. power failure) could throw the tank off balance for a week or so.