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Never done one but sounds like a cool idea. What you could do is get fish that resemble the superheroes like superman red and blue get a big school of neon tetra. See if you can find some superhero decorations and you'll be set.
Holy cow a 130!? You can do alot! First off what budget? If you are willing to spend some cash (and time I might add) then buying a bunch of the lego hero kits for it would be amazing! Or you could just buy some of the action figures and accessories for probably cheaper.
I have those statues too for my kid's tank for his birthday. I am deliberating returning them because the only online review for the Capt America one said that the paint bubbled and peeled off within a month. It's hard to judge off just one review.
I'm considering going with a Lego theme instead. Someone on the board suggested it and now I feel terrible I can't remember who it was off the top of my head (take credit if you're reading this!)