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My girlfriend wants to add discus and angelfish.. Would this work?
Also, what else would I be able to add in conjunction with the neons, discuss, knifefish and angels without any problems??
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Discus are very difficult to keep, and
IMO should be in a species tank. At the very least kept with cardinals instead of neons. Like menagerie said, angels may eat the neons. It sounds like you guys are going for a South American set up, and with a tank that big, I would go for a lot of plants and some small cichlids. Some of the easier fish to care for from that region are the many tetras, cory catfish--some of the harder are rams and the aforementioned discus. If you would be willing to return the neons (or willing to consider neons food), some of the bigger cichlids from that region will work nicely in a tank that size.
Basically, in a tank that size, you could have a slew of schooling fish (my favorite being a school of hatchets, a school of cardinals, and a school of cories) or a species tank with one or two good sized cichlids.
In any case, you are taking a wise step in asking before buying

. Good Luck!